JEE ADVANCED 2013 CHEMISTRY SYLLABUS, CHEMISTRY SYLLABUS JEE ADVANCED
JEE Advanced 2013 Chemistry Syllabus
Physical chemistry
General topics: Concept of atoms and molecules;
Dalton’s atomic theory; Mole concept; Chemical formulae; Balanced
chemical equations; Calculations (based on mole concept) involving
common oxidation-reduction, neutralisation, and displacement reactions;
Concentration in terms of mole fraction, molarity, molality and
normality.
Gaseous and liquid states: Absolute scale of
temperature, ideal gas equation; Deviation from ideality, van der Waals
equation; Kinetic theory of gases, average, root mean square and most
probable velocities and their relation with temperature; Law of partial
pressures; Vapour pressure; Diffusion of gases.
Atomic structure and chemical bonding:
Bohr model, spectrum of hydrogen atom, quantum numbers; Wave-particle
duality, de Broglie hypothesis; Uncertainty principle; Qualitative
quantum mechanical picture of hydrogen atom, shapes of s, p and d
orbitals;
Electronic configurations of elements (up to atomic number
36); Aufbau principle; Pauli’s exclusion principle and Hund’s rule;
Orbital overlap and covalent bond; Hybridisation involving s, p and d
orbitals only; Orbital energy diagrams for homonuclear diatomic
species; Hydrogen bond; Polarity in molecules, dipole moment
(qualitative aspects only); VSEPR model and shapes of molecules (linear,
angular, triangular, square planar, pyramidal, square pyramidal,
trigonal bipyramidal, tetrahedral and octahedral).
Energetics: First law of thermodynamics; Internal
energy, work and heat, pressure-volume work; Enthalpy, Hess’s law; Heat
of reaction, fusion and vapourization; Second law of thermodynamics;
Entropy; Free energy; Criterion of spontaneity.
Chemical equilibrium: Law of mass action;
Equilibrium constant, Le Chatelier’s principle (effect of concentration,
temperature and pressure); Significance of ΔG and ΔG° in chemical
equilibrium; Solubility product, common ion effect, pH and buffer
solutions; Acids and bases (Bronsted and Lewis concepts); Hydrolysis of
salts.
Electrochemistry: Electrochemical cells and cell
reactions; Standard electrode potentials; Nernst equation and its
relation to ΔG; Electrochemical series, emf of galvanic cells; Faraday’s
laws of electrolysis; Electrolytic conductance, specific, equivalent
and molar conductivity, Kohlrausch’s law; Concentration cells.
Chemical kinetics: Rates of chemical reactions;
Order of reactions; Rate constant; First order reactions; Temperature
dependence of rate constant (Arrhenius equation).
Solid state: Classification of solids, crystalline
state, seven crystal systems (cell parameters a, b, c, α, β, γ), close
packed structure of solids (cubic), packing in fcc, bcc and hcp
lattices; Nearest neighbours, ionic radii, simple ionic compounds, point
defects.
Solutions: Raoult’s law; Molecular weight
determination from lowering of vapour pressure, elevation of boiling
point and depression of freezing point.
Surface chemistry: Elementary concepts of adsorption
(excluding adsorption isotherms); Colloids: types, methods of
preparation and general properties; Elementary ideas of emulsions,
surfactants and micelles (only definitions and examples).
Nuclear chemistry: Radioactivity: isotopes and
isobars; Properties of α, β and γ rays; Kinetics of radioactive decay
(decay series excluded), carbon dating; Stability of nuclei with respect
to proton-neutron ratio; Brief discussion on fission and fusion
reactions.
Inorganic Chemistry
Isolation/preparation and properties of the following non-metals:
Boron, silicon, nitrogen, phosphorus, oxygen, sulphur and halogens;
Properties of allotropes of carbon (only diamond and graphite),
phosphorus and sulphur.
Preparation and properties of the following compounds:
Oxides, peroxides, hydroxides, carbonates, bicarbonates, chlorides and
sulphates of sodium, potassium, magnesium and calcium; Boron: diborane,
boric acid and borax; Aluminium: alumina, aluminium chloride and alums;
Carbon: oxides and oxyacid (carbonic acid); Silicon: silicones,
silicates and silicon carbide;
Nitrogen: oxides, oxyacids and ammonia;
Phosphorus: oxides, oxyacids (phosphorus acid, phosphoric acid) and
phosphine; Oxygen: ozone and hydrogen peroxide; Sulphur: hydrogen
sulphide, oxides, sulphurous acid, sulphuric acid and sodium
thiosulphate; Halogens: hydrohalic acids, oxides and oxyacids of
chlorine, bleaching powder; Xenon fluorides.
Transition elements (3d series): Definition, general
characteristics, oxidation states and their stabilities, colour
(excluding the details of electronic transitions) and calculation of
spin-only magnetic moment;
Coordination compounds: nomenclature of
mononuclear coordination compounds, cis-trans and ionisation
isomerisms, hybridization and geometries of mononuclear coordination
compounds (linear, tetrahedral, square planar and octahedral).
Preparation and properties of the following compounds: Oxides and chlorides of tin and lead; Oxides, chlorides and sulphates of Fe2+, Cu2+ and Zn2+; Potassium permanganate, potassium dichromate, silver oxide, silver nitrate, silver thiosulphate.
Ores and minerals: Commonly occurring ores and minerals of iron, copper, tin, lead, magnesium, aluminium, zinc and silver.
Extractive metallurgy: Chemical principles and
reactions only (industrial details excluded); Carbon reduction method
(iron and tin); Self reduction method (copper and lead); Electrolytic
reduction method (magnesium and aluminium); Cyanide process (silver and
gold).
Principles of qualitative analysis: Groups I to V (only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2+, Mn2+ and Mg2+); Nitrate, halides (excluding fluoride), sulphate and sulphide.
Organic Chemistry
Concepts: Hybridisation of carbon; Sigma and
pi-bonds; Shapes of simple organic molecules; Structural and geometrical
isomerism; Optical isomerism of compounds containing up to two
asymmetric centres, (R,S andE,Z nomenclature
excluded); IUPAC nomenclature of simple organic compounds (only
hydrocarbons, mono-functional and bi-functional compounds);
Conformations of ethane and butane (Newman projections);
Resonance and
hyperconjugation; Keto-enol tautomerism; Determination of empirical and
molecular formulae of simple compounds (only combustion method);
Hydrogen bonds: definition and their effects on physical properties of
alcohols and carboxylic acids; Inductive and resonance effects on
acidity and basicity of organic acids and bases; Polarity and inductive
effects in alkyl halides; Reactive intermediates produced during
homolytic and heterolytic bond cleavage; Formation, structure and
stability of carbocations, carbanions and free radicals.
Preparation, properties and reactions of alkanes:
Homologous series, physical properties of alkanes (melting points,
boiling points and density); Combustion and halogenation of alkanes;
Preparation of alkanes by Wurtz reaction and decarboxylation reactions.
Preparation, properties and reactions of alkenes and alkynes:
Physical properties of alkenes and alkynes (boiling points, density and
dipole moments); Acidity of alkynes; Acid catalysed hydration of
alkenes and alkynes (excluding the stereochemistry of addition and
elimination); Reactions of alkenes with KMnO4 and ozone; Reduction of
alkenes and alkynes; Preparation of alkenes and alkynes by elimination
reactions; Electrophilic addition reactions of alkenes with X2, HX, HOX
(X=halogen) and H2O; Addition reactions of alkynes; Metal acetylides.
Reactions of benzene: Structure and aromaticity;
Electrophilic substitution reactions: halogenation, nitration,
sulphonation, Friedel-Crafts alkylation and acylation; Effect of o-, m- and p-directing groups in monosubstituted benzenes.
Phenols: Acidity, electrophilic substitution
reactions (halogenation, nitration and sulphonation); Reimer-Tieman
reaction, Kolbe reaction.
Characteristic reactions of the following (including those mentioned
above): Alkyl halides: rearrangement reactions of alkyl carbocation,
Grignard reactions, nucleophilic substitution reactions;
Alcohols:
esterification, dehydration and oxidation, reaction with sodium,
phosphorus halides, ZnCl2/concentrated HCl, conversion of alcohols into
aldehydes and ketones; Ethers:Preparation by Williamson’s Synthesis;
Aldehydes and Ketones: oxidation, reduction, oxime and hydrazone
formation; aldol condensation, Perkin reaction;
Cannizzaro reaction;
haloform reaction and nucleophilic addition reactions (Grignard
addition); Carboxylic acids: formation of esters, acid chlorides and
amides, ester hydrolysis; Amines: basicity of substituted anilines and
aliphatic amines, preparation from nitro compounds, reaction with
nitrous acid, azo coupling reaction of diazonium salts of aromatic
amines, Sandmeyer and related reactions of diazonium salts; carbylamine
reaction; Haloarenes: nucleophilic aromatic substitution in haloarenes
and substituted haloarenes (excluding Benzyne mechanism and Cine
substitution).
Carbohydrates: Classification; mono- and
di-saccharides (glucose and sucrose); Oxidation, reduction, glycoside
formation and hydrolysis of sucrose.
Amino acids and peptides: General structure (only primary structure for peptides) and physical properties.
Properties and uses of some important polymers: Natural rubber, cellulose, nylon, teflon and PVC.
Practical organic chemistry: Detection of elements
(N, S, halogens); Detection and identification of the following
functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde
and ketone), carboxyl, amino and nitro; Chemical methods of separation
of mono-functional organic compounds from binary mixtures.
JEE ADVANCED 2013 CHEMISTRY SYLLABUS, CHEMISTRY SYLLABUS JEE ADVANCED, JEE ADVANCED 2013 CHEMISTRY SYLLABUS, CHEMISTRY SYLLABUS JEE ADVANCED
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